A rare uninodal 9-connected metal−organic framework (Zn 3 (TAA) 3 (H 2 O) 3 ·(1,4-dioxane) ( MOF 1 ) (TAA = 1-H-tetrazole-5-acetate) was synthesized, structurally characterized, and topologically rationalized as a vnd net, exhibiting permanent porosity, and solvent-dependent luminescence properties.
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Zhang et al. (2010) studied this question.