All articles of this category N -(1,1-Disubstituted-allyl)anilines are rearranged cleanly and in high yield to 2-(3,3-disubstituted-allyl)anilines using a catalytic amount of p -toluenesulfonic acid in acetonitrile/water (10:1). amino-Claisen - rearrangement - aromatic amines - alkenes - alkynes
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Cooper et al. (2001) studied this question.
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