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Four new alkylnickel(II)–phosphine complexes, NiR2(PR′3)2 (R=CH3, C2H5; PR′3=triethylphosphine (PEt3), tributylphosphine (PBu3), 1,2-bis(diphenylphosphino)ethane(dpe)) and Ni(CH3)(acac)(PEtPh2) (PEtPh2=ethyldiphenylphosphine), have been prepared by reactions of Ni(acac)2 with AlR2(OC2H5) in the presence of phosphine ligands.
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Yamamoto et al. (1982) studied this question.
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