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The rotational analysis of the 0-0, 1-1, 0-1 and 1-2 bands of the γ system of SiF has been completed. The upper state C is most probably 2 Δ (case b ). Derived constants for this state, in units of cm -1 , are as follows: T 00 = 39 537.45 (relative to × 2 II 1/2 ) Δ G 1/2 = 878.38 B 0 = 0.600 68 α = 0.005 39 A 0 = 2.46.
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Appelblad et al. (1968) studied this question.
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