A meso-N-pyrrole porphyrin converts into a π-extended porphyrin forming an indolizine-3-one motif. The indolizine-3-one frame opens a lactam subunit preserving a six-membered, heterocyclic structure fused with the main macrocycle. The optical properties of formed derivatives follow the structural modifications giving the absorbance and emission eventually modulated by the NH-centered modifications of the fused unit.
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Hurej et al. (2016) studied this question.
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