Magnetic circular dichroism (MCD) spectra of some thiadiazoles have revealed the characteristic π → π* transitions in cata-condensed thiadiazoles. Within the framework of the PPP method quantum mechanical calculations have been carried out in order to give a reasonable explanation for the MCD spectra, resulting in a fairly good agreement between the experimental and theoretical Faraday parameters
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Tajiri et al. (1983) studied this question.
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