electrode modified with the sensitizer and a molecular water oxidation catalyst generated higher photocurrent than reference cells that have electrodes modified with either the photosensitizer or the catalyst under visible light (λ > 500 nm) illumination. Oxygen evolution was confirmed after photolysis by GC and GC-MS analyses using isotope-labeling experiments. The large molar extinction coefficients of the ring-contracted porphyrin in the visible region enabled kinetic analysis by time-resolved transient absorption spectroscopy, which also supported the photocatalytic activity.
No takes yet. Share an insight, caveat, or question.
Yamamoto et al. (2016) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: