Ultraviolet laser photolysis of dilute mixtures of F2 and C2H4 in solid argon form a 2-fluoroethyl radical by addition of translationally ‘hot’ as well as thermal F atoms to ethene; at T > 20 K the major channel is the thermal reaction, which converts up to 25% of ethene to 2-fluoroethyl radical.
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Benderskii et al. (1995) studied this question.
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