Initiation of the polymerization of 2‐vinylpyridine by organomagnesium compounds in hydrocarbon solvents, was obtained without side reactions on the pyridine rings. The resulting active centres are unsymmetrical. They are stable and stereospecific, leading to living polymers with an isotacticity degree of about 0,9.
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Soum et al. (1980) studied this question.
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