An interpretation is given for various anomalies reported by C. C. Costain concerning the rotation spectrum of CHF3 and CDF3 in the excited vibrational state ν6 = 1. These anomalies are related to an essential resonance between levels K = 0, [Formula: see text], and K = ± 2, l6 = ±1, this resonance being accidentally strong, particularly in the case of CDF3.
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Maes et al. (1965) studied this question.
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