The title complexes containing platinum-carbon [sgrave]-bonds and triethylphosphine ligands were synthesized and their thermal properties were examined. The complexes composed of a four-ring system showed enantiotropic nematic phases, though they have a very large lateral group. Direction of the ester group of the complexes strongly influenced the thermal stability of mesophases.
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Kaharu et al. (1992) studied this question.
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