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By wrapping the inorganic core of the cluster with hydrocarbons (Cp* substituents of the Cp*TiF2 building blocks), the very large dimetallic aggregates 1 (core of cluster shown on the right) and 2 can be dissolved in organic solvents. In this way a source of “soluble NaF and CaF2” in common solvents is available for organometallic chemistry. Compounds 1 and 2 are obtained from the reaction of [Cp*TiF3] with Na/Hg and Ca/Hg alloy, respectively. [CpTi14Na18F48(thf)6]1[(Cp*TiF2)6CaF2(thf)2] 2
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Liu et al. (1995) studied this question.
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