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Summary: Statistical random copolymers of 1H,1H‐perfluorooctyl methacrylate and 2‐dimethylaminoethyl methacrylate, poly(FOMA‐co‐DMAEMA), effectively stabilized the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide. Free‐flowing, micron‐sized spherical PMMA particles could be produced with poly(FOMA‐co‐DMAEMA) containing 34 w/w% FOMA. SEM image of PMMA particles prepared with poly(FOMA‐co‐DMAEMA) (34:66). image SEM image of PMMA particles prepared with poly(FOMA‐co‐DMAEMA) (34:66).
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Hwang et al. (2005) studied this question.
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