Carbon atoms were generated by two photon absorption in carbon suboxide C3O2. Two photon laser induced fluorescence (LIF) excitation spectra using the 3 3DJ′←2 3PJ″ at 287 nm and 4 1P1←2 1D2 at 284 nm transitions were intense showing that LIF is a convenient detection method for carbon atoms in their ground 3P and first excited 1D states. Calculated values of the relative intensities of the seven allowed J′←J″ transitions were in good agreement with experimental values.
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Das et al. (1983) studied this question.
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