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Two new pentaerythritol-functionalised 2,2′:6′,2″-terpyridine (tpy) derivatives have been prepared. One contains four tpy metal-binding domains, whereas the other contains one tpy domain and three pendant CH2OH groups. The combination of these components with ruthenium-containing building blocks has allowed the specific and stepwise synthesis of tetranuclear and hexadecanuclear metallodendrimers.
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Constable et al. (1998) studied this question.
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