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A procedure for the [Cp*CoIII]‐catalyzed direct CH amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 [{Cp*MCl2}2] complexes revealed the unique efficiency of the cobalt catalyst.
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Park et al. (2015) studied this question.
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