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The reactions of fluorine atoms with normal and deuterated methanols have been studied at low pressure using a fast discharge flow reactor. Samples were withdrawn continuously via a molecular beam sampling system and were analyzed by a mass‐spectrometer. — The rate constants have been determined relative to the reaction magnified image for the reactions (1)–(4) were found as k1a/k1b = 0.40/0.60; k2a/k2b = 0.37/0.63; k3a/k3b = 0.39/0.61; and k4a/k4b = 0.36/0.64.
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Khatoon et al. (1988) studied this question.
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