Dinuclear alkynylcopper(I) complexes have been found to be the active pre‐catalysts in copper‐catalysed cycloaddition of azides and terminal alkynes (CuAAC). These copper(I) ladderane polymers are used in “on water” CuAAC reactions, with loadings as low as 1 mol‐%.
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Buckley et al. (2010) studied this question.
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