Synthesis of Poly(methyl methacrylate) Nanosize Particles by Differential Microemulsion Polymerization

Poly(methyl methacrylate) nanosize particles were synthesized by a differential microemulsion polymerization process. Sodium dodecylsulfate and ammonium persulfate were used as the surfactant and initiator, respectively. The effects of reaction conditions on the particle size have been investigated. A particle size of less than 20 nm in diameter has been achieved with surfactant/monomer and surfactant/water weight ratios of 1:18 and 1:120, i.e. much milder conditions than those previously reported in the literature. TEM image of nanoparticles prepared via differential microemulsion polymerization. magnified image TEM image of nanoparticles prepared via differential microemulsion polymerization.