Asymmetric Metal Halide Film With Suppressed Leakage Current for High Sensitive X-Ray Detection and Imaging

Metal halides have been demonstrated to be promising candidates for X-ray detectors. However, its large leakage current caused by the severe ion migration and intrinsic defect substantially degrades device performance. In this work, an asymmetric BA2CsPb2I7-CsPbI3 planar heterojunction X-ray detector is designed to suppress the leakage current. Both experimental and theoretical calculations demonstrate that: 1) enlarged ion migration energy (0.80 eV) and conductivity mutation at the interface ensure stable baseline and suppress leakage current; 2) CsPbI3 ensures effective absorption of X-ray, while BA2CsPb2I7 induces larger bulk resistance, which is expected to achieve higher photocurrent and lower dark current. Finally, the obtained X-ray detector exhibits negligible baseline drift, faster response, and smaller leakage current compared to the CsPbI3 counterparts. Specifically, the device exhibits a detection limit of0.092 ~μGyₐᵢᵣ/s, and the CsPbI3-based device was2.63 ~μGyₐᵢᵣ/s.