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The aluminum chloride-catalyzed acylation of α-silylallylic selenides with acid chlorides at −78 °C produced γ-acylated vinylic selenides regioselectively. α-Silylallylic selenides in some cases underwent [1,3] shifts of the selenenyl groups by the catalysis with aluminum chloride, affording γ-silylallylic selenides. This regioselective acylation of allylic selenides provides a new route to dihydrojasmone.
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Hiroi et al. (1986) studied this question.
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