The energies of defect clusters In Mn 1–x O, Fe 1–x O. Co 1–x O, and Ni 1–x ,O have been calculated using molecular orbited theory. The results indicate that (i) relatively large extended defects of a zinc blende type coordination are stable in MnO and FeO, (ii) only small defects are stable in CoO, and (iii) no defect structures are stable in NiO.
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Grimes et al. (1986) studied this question.
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