The first enantioselective Brønsted acid‐catalyzed electrocyclization‐protonation reaction has been developed which provides a number of different cyclopentenones in good yields and with high enantioselectivities. The stereodetermining step of this asymmetric Nazarov cyclization reaction is an asymmetric Brønsted acid‐catalyzed kinetic protonation.
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Rueping et al. (2009) studied this question.
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