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The influence of lipophilic, electrically neutral surfactants added to the membrane on the ion transfer resistance between an aqueous sample and a polymeric ion‐selective membrane has been studied by electric impedance spectroscopy and potentiometry. An increase in the surface resistance and a shift of the apparently super‐Nernstian response to lower sample ion activities has been observed when using the nonpolar bis(2‐ethylhexyl) sebacate as plasticizer.
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Muslinkina et al. (2004) studied this question.
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