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Perfluoroalkyl iodides were added in very good yields to 1,2‐dialkyl substituted double bonds of e.g. petroselinic acid initiated by lead/copper(II) acetate in methanol and by copper without solvent, respectively. Using the new initiator system lead/copper(II) acetate, we also obtained good yields in the additions of perfluoroalkyl iodides to allyl alcohol and ω‐unsaturated alcohols and of perfluoroalkyl 1,ω‐diiodides to methyl 10‐undecenoate.
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Metzger et al. (1996) studied this question.
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