Clusters containing 18, 45, and 50 silver atoms can be synthesized from the reaction of AgCl with PhP(SiMe3)2 in the presence of PnPr3. The structures of the phosphinidine‐bridged silver clusters formed depends upon the temperature and the stoichiometric ratio of the reactants. [ Ag50(PPh)20Cl7P(PnPr3)13] is the biggest known silver cluster and one of the largest structurally characterized cluster complexes to date.
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Fenske et al. (1997) studied this question.
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