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Methyl 1H‐benzimidazol‐2‐ylcarbamate (carbendazim or MBC) catalyzes the reduction of CoII at mercury electrodes in sodium barbital/nitric acid/sodium chloride media. On the basis of a detailed study of the CoII prewave induced by carbendazim, a mechanism for the electrode reaction is proposed and adequate conditions for the analytical determination of carbendazim by differential pulse voltammetry are established. Based on this finding, a voltammetric method for the indirect determination of methyl[1‐(butylcarbamoyl)‐1H‐benzimidazol‐2yl]carbamate (benomyl) is described, following the conversion of benomyl to carbendazim.
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Alvarez et al. (1997) studied this question.
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