Ti ∕ Au Ohmic contacts on heavily Al-doped (n∼1019cm−3) n-ZnO produce low specific contact resistivity of 2.4×10−7Ωcm2 in the as-deposited condition and extremely low minimum values of 6×10−8Ωcm2 after annealing at 300°C.The contact resistance is independent of measurement temperature after low temperature anneals, suggesting that tunneling is the dominant transport mechanism in the contacts. The contact morphology roughens after annealing at 150°C and Auger electron spectroscopy depth profiling shows Zn outdiffusion through the metal and intermixing of Au and Ti. However, the morphology does not significantly worsen after anneals at 450°C. This metallization scheme looks very attractive for the n-electrode of ZnO-based light-emitting diode structures.
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Chen et al. (2006) studied this question.
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