The results of HXR calculations of the 3d subshell absorption spectra of Rb I and Sr I are presented. Both the transition energies and their intensities are compared with experiment and the resulting assignments of the experimental peaks are discussed in relation to those obtained by self-consistent field calculations and by the Z+1 approximation. The limitations in the applicability of the Z+1 model in cases where strong s-d mixing is induced by wavefunction collapse are indicated.
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Mansfield et al. (1982) studied this question.
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