We propose a type of pn-junction not formed by impurity-doping, but rather by grading the Al composition in an AlxGa1−xN thin film, resulting in alternating p and n conducting regions due to polarization charge. By linearly grading AlxGa1−xN from 0% to x (x ≤ 30%) and back to 0% Al, a polarization induced pn-junction is formed, even in the absence of any impurity doping. X-ray diffraction reciprocal space maps are used to determine the strain state of the different graded composition samples. Polarization induced doping also provides a solution to the problem of p-type doping efficiency for III-nitrides.
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Li et al. (2012) studied this question.
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