Spectroscopy of carbon particles, fullerenes, and carbon chain molecules was the subject of a considerable part of my research work, as described in this article. In almost all cases, there existed a tight connection to problems in astrophysics and astrochemistry, aiming at a better understanding of interstellar matter. The bulk synthesis of fullerenes was a by-product of these efforts.
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Wolfgang Krätschmer (2013) studied this question.