From our recent research on ice Ih (hexagonal ice), we deduce that free OH groups exist at the ice surface and that dangling OH influences the interior of the proton-disordered ice. Additionally, exploiting recent research by others on water molecular clusters, we propose a new interpretation for the Raman OH stretching vibration of ice Ih. We deconvolute the Raman OH stretching vibration of ice Ih into four sub-bands, with each sub-band being ascribed to OH vibrations engaged in different types of hydrogen bonding.
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Sun et al. (2009) studied this question.
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