The present paper describes a synergistic effect in the Pd-catalyzed Suzuki–Miyaura cross-coupling reaction. The chemoselective cross-coupling reaction of (diborylmethyl)trimethylsilane and aryl halides proceeded at room temperature when a silver salt and KOH were added. The reaction gave benzylboronate derivatives bearing a trimethylsilyl group at the benzylic position.
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Endo et al. (2013) studied this question.
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