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April 1, 1993Angewandte Chemie International Edition in English

A New Type of Hexanuclear Iron( III ) Hydroxo(oxo) Cluster

C.J. Harding Richard K. Henderson Annie K. Powell

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Abstract

Bridging μ3‐oxo and μ2‐hydroxo ligands characterize the structure of the cluster anion 1, which can be prepared as a highly soluble K or Na salt in water. The structure of 1 can be viewed as two parallel, μ3‐oxo‐bridged Fe3 triangles joined by μ‐hydroxo bridges or as two Fe4 butterfly structures with shared wing tips. Cluster 1 has more short FeFe separations than all other related compounds, and its effective magnetic moment μeff increases dramatically at low temperatures. This magnetic behavior is not completely understood. equation image

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Cite This Study

Harding et al. (1993) studied this question.

synapsesocial.com/papers/6a9ba7a1653d0dfe315a8cf2 https://doi.org/10.1002/anie.199305701

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

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