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September 18, 1998Inorganic Chemistry

NH4VOPO4·H2O, a New One-Dimensional Ammonium Vanadium(IV) Phosphate Hydrate

Zsolt Bircsk William T. A. Harrison

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Abstract

The new vanadium(IV) phosphate NH4VOPO4·H2O has strong one-dimensional character and consists of double chains of VO5 square pyramids and PO4 tetrahedra, sharing vertexes. A V−OH2 grouping is present, and hydrogen bonds involving the H2O and NH4+ moieties are important in stabilizing the overall crystal structure.

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Cite This Study

Bircsk et al. (1998) studied this question.

synapsesocial.com/papers/6a9be60849ab707c248504ff https://doi.org/10.1021/ic971481z

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Mechanistic aspects of maleic anhydride synthesis from C4 hydrocarbons over phosphorus vanadium oxideOriginal Research · 1988 · 822 citations
2Role of ion exchange in solid-state chemistryOriginal Research · 1988 · 821 citations
3Redox intercalation reactions of vanadium oxide phosphate dihydrate (VOPO4.2H2O) with mono- and divalent cationsOriginal Research · 1985 · 99 citations
4Giant Voids in the Hydrothermally Synthesized Microporous Square Pyramidal−Tetrahedral Framework Vanadium Phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2OOriginal Research · 1996 · 213 citations
5Aqueous coordination chemistry of vanadocene dichloride with nucleotides and phosphoesters. Mechanistic implications for a new class of antitumor agentsOriginal Research · 1986 · 107 citations

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Hydrothermal synthesis and structural characterization of reduced vanadium phosphates, α-Rb[VIII(HPO4)2], β-Rb[VIII(HPO4)2] and NH4[VIII(HPO4)2], octahedral-tetrahedral framework solids1995
Synthesis, Structure, and Magnetic Properties of (NH4)VOPO4: A Structure with One-Dimensional Chains of VO6 Octahedra1994
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