An accurate value for the first ionization potential of zirconium of 53 506.0(3) cm−1 has been obtained from convergence limits of high lying Rydberg series observed using two laser, field- ionization spectroscopy of an atomic beam of zirconium. The new value is consistent with analysis of s-electron binding energies of other second transition series elements.
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Hackett et al. (1986) studied this question.
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