Measurements of charge mobility and diffusion coefficient of conjugated electroluminescent polymers by time-of-flight method

Charge mobilities (μ) and diffusion coefficients (D) of hole (μh, Dh) and electron (μe, De) of the conjugated electroluminescent polymers, poly(phenylene vinylene)s and polyfluorenes, have been measured by fitting of a theoretical photocurrent transient equation to time-of-flight photocurrent transients. The μ so obtained are in agreement with those from inflection points of photocurrent transients. The D value lumps all factors together that cause the dispersion of carriers, and the parameter Dq/μkT can be used as an indicator of the degree of dispersion. This fitting method allows extracting μ and D from highly dispersive photocurrent transients, even for the case in which no inflection point appears.