The esterification of a representative redox-active polyoxometalate (POM), [H4P2V3W15O62]5−, with methanol and two simple dendrimers each having four tris(hydroxymethyl) termini has been investigated. The tetra(polyoxometalate) dendrimers are hydrolytically stable, and 1 has been shown to catalyze the oxidation of tetrahydrothiophene by peroxides.
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Zeng et al. (2000) studied this question.
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