Transition‐Metal Silyl Complexes, 34. – A Dinuclear Gold Silyl Complex with Gold‐ Gold Interaction Between an (R3P)2Au and an (R′3,Si)ClAu Unit Ph2MeP‐Au‐Cl reacts with Ph2MeP‐Au‐SiPh3 to form the dinuclear complex (Ph2MeP)2Au2(Cl)SiPh3, which is in equilibrium with its starting compounds. An X‐ray structure analysis reveals that it consists of a (Ph2MeP)2Au and a (Ph3Si)ClAu unit, which are held together by Au‐Au interaction [298.07(4) Pm]. The approximately linear AuL2 units are orthogonal to each other.
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Meyer et al. (1990) studied this question.
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