A series of naphthalene‐bridged P,N‐type sulfoximine ligands and their iridium complexes have been synthesized. They were applied in the enantioselective hydrogenation of quinoline derivatives, and enantioselectivities up to 92% ee have been achieved in the hydrogenation of 2‐methylquinoline.
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Lu et al. (2008) studied this question.
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