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December 3, 2001Angewandte ChemieOpen Access

A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes

Jörg Blankenstein Andreas Pfaltz

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Abstract

Leicht herstellen lassen sich beide Enantiomere der Phosphinit-Oxazolin-Liganden 1 aus D- und L-Serin (siehe Schema). Iridiumkomplexe dieser Liganden (die Struktur eines Komplexes ist gezeigt) sind hocheffiziente Katalysatoren für die enantioselektive Hydrierung nichtfunktionalisierter Alkene. R1=Ferrocenyl, Aryl; R2=Alkyl, Benzyl.

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Blankenstein et al. (2001) studied this question.

synapsesocial.com/papers/6a9c9a0744c4a4ef85b67445 https://doi.org/10.1002/1521-3757(20011203)113:23<4577::aid-ange4577>3.0.co;2-p

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