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Abstract 1,2-cis-Ribofuranosides are stereoselectively synthesized in high yields by the reaction of β-ribofuranosyl fluoride and alcohols in the presence of stannous chloride and trityl perchlorate. Under similar condition, α-arabinofuranosyl fluoride reacts with cholestanol to give 1,2-cis-arabinofuranoside predominatly.
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Mukaiyama et al. (1983) studied this question.
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