A one-stage procedure for the stereoselective α-glucosylation of alcohol with 2,3,4,6-tetra-O-benzyl-α-d-glucopyranose and a mixture of methanesulfonic acid, cobalt(II) bromide, and tetraethylammonium perchlorate is described. The mechanism of the glucosylation reaction is discussed.
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Koto et al. (1982) studied this question.
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