The effect of a number of iron complexing agents on the persulfate‐bisulfite catalysis of acrylonitrile polymerization was studied. Several complexing agents were found to be effective in retarding suspension polymerization of acrylonitrile with this redox system. A relationship was found betweeen the redox potential of the iron complex and polymerization rate. Evidence was shown that the persulfate‐bisulfite polymerization of acrylonitrile requires the presence of iron or other metal ions.
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Charles Campbell (1958) studied this question.
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