A Uranyl-Organic Framework Featuring Two-Dimensional Graphene-like Layered Topology for Efficient Iodine and Dyes Capture

A novel uranyl–organic framework [(CH 3 ) 2 NH 2 ][UO 2 (TATAB)]·2DMF·4H 2 O (U-TATAB) was assembled through the solvothermal synthesis of UO 2 (CH 3 COO) 2 ·2H 2 O and triazine tricarboxylate linker H 3 TATAB (H 3 TATAB = 4,4′,4″-s-triazine-1,3,5-triyltri- p -aminobenzoate). It was characterized by single-crystal X-ray diffraction, elemental analysis, IR, powder X-ray diffraction, and thermogravimetric microanalysis. It is worth mentioning that U-TATAB exhibits an original arrangement of structures with interesting topology. Structural analysis confirmed that U-TATAB displays an interesting two-dimensional graphene-like layered topology. In order to broaden its functional characteristics, we first investigated the functional adsorbent U-TATAB for iodine capture in cyclohexane solution and for the removal of dye in aqueous solution. Large porosity, unique structure character, and the π-electron walls made of TATAB make the material a promising functional absorbent exhibiting excellent adsorption performance for iodine and dye molecules. Most notably, this is the first case of a uranyl–organic framework built by secondary building unit (SBU) [UO 2 (RCOO) 3 ] – and extended trigonal triazine tricarboxylate ligand H 3 TATAB with amino functional groups.