Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF(3))(2)/NPMoV catalytic system, leading to the corresponding (E)-allylamines in good yield and selectivity through the formation of (eta(3)-allyl)palladium(II) trifluoroacetate species as a possible key intermediate.
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Shimizu et al. (2010) studied this question.