The crystallographically characterised, five-coordinate complex [RuCl2(o-diphenylphosphino-N,N-dimethyianiline){P(p-tolyl)3}] reversibly binds H2 and N2 to form η2-H2 and σ-N2 species, respectively; the former reacts with base to generate the chloro(hydrido) derivative.
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Mudalige et al. (1993) studied this question.
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