Palladium complexes of 2-pyridyldiphenylphosphine anchored on polystyrene, polymethylmethacrylate and styrene-methylmethacrylate copolymer form highly active heterogeneous catalysts for the alkoxycarbonylation of terminal alkynes with activities approaching those obtained under homogeneous conditions.
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Doherty et al. (2005) studied this question.
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