Answers are grounded in this paper and cite their sources.
The Al4P4 cube in [iBuAl(μ3-PSiPh3]4 is not only aesthetically attractive. Its behavior on thermal loading makes it also of interest as precursor for the III/V semiconductor AlP. Already at 150°C the substituents are split off as Ph3SiH and isobutene. Elevation of the temperature to 500 °C leads to pure A1P.
No takes yet. Share an insight, caveat, or question.
Cowley et al. (1990) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: