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Kinetics of the vinyl polymerization of acrylonitrile initiated by the redox system cyclohexanone/V5 + were investigated in aqueous sulphuric acid in the temperature range of 35—50°C and the rates of polymerization and of V5 + disappearance etc. were measured. From the result it was concluded that the polymerization reaction is initiated by an organic free radical arising from the V5 +‐cyclohexanone reaction and terminated by V5 + ions. A suitable kinetic scheme was proposed and the various rate and energy parameters were evaluated.
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Mohanty et al. (1974) studied this question.
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